標題: Structural transformations in dinuclear zinc complexes involving Zn-Zn bonds
作者: Tsai, Yi-Chou
Lu, Duan-Yen
Lin, Yang-Miin
Hwang, Jenn-Kang
Yu, Jen-Shiang K.
生物科技學系
Department of Biological Science and Technology
公開日期: 2007
摘要: Reduction of Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2) with 4 equiv. of KC8 resulted in a dramatic structural transformation into [(eta(2)- Me2Si( NDipp)(2)) ZnZn(eta(2)- Me2Si( NDipp)(2))](2-) featuring a Zn - Zn bond instead of [Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2)](2-); the mechanism of the observed structural transformations arising from the Zn - Zn bond formation involving the intermediate of [Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2)](-) was elucidated by elaborate computations.
URI: http://hdl.handle.net/11536/11364
http://dx.doi.org/10.1039/b707396h
ISSN: 1359-7345
DOI: 10.1039/b707396h
期刊: CHEMICAL COMMUNICATIONS
Issue: 40
起始頁: 4125
結束頁: 4127
顯示於類別:期刊論文


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